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Dutch students create modular electric car "you can repair yourself"
(www.dezeen.com)
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Any electricity used for electrolysis came from gasoline. If you turn on a bunch of electronics in your car, your alternator gets harder to spin and your engine consumes more fuel to do it. Then you're putting energy into breaking bonds which is energy you will partially (but not fully) recover by burning them. It's impossible for this system to result in a more efficient engine.
Thanks