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xkcd #2929: Good and Bad Ideas
(imgs.xkcd.com)
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The only correct way to cut (not too gigantic) round pizza is into six parts so you get equilateral triangles (well, modulo a curved section) which is ideal for holding.
Home-made pizza rarely if ever is round, though, in which you probably don't want to go for squares but eyeball some appropriately-sized rectangles.