This might work: https://discuss.kde.org/t/change-color-or-theme-of-specific-window/1884/6
I'm not familiar with Unity Mod Manager, so hard to say or give detailed instructions.
If you happen to know how to run Unity Mod Manager from the terminal, the easiest way to check whether it will work, is by first running export GTK_THEME=Default and then running Unity Mod Manager in the same terminal.
This export command sets an environment variable (GTK_THEME). In case Unity Mod Manager respects the GTK theme of your system, it will presumably respect that environment variable.
From what I've quickly read up on Unity Mod Manager, it is implemented in C#, so I'm guessing it does not use GTK directly (but might still try to emulate its theme from the GTK theme) and well, it might behave weirdly under Linux in general...
(There's a button in the top-right of the screenshot.)