I'm playing on a 65" 4k OLED with 5.1 surround sound. It's awesome on the PS5! I have the PC version too and movement and the camera are a lot better on PS5. Inventory management is better on PC, and some world interactions are easier. The graphics are more detailed on my PC with a 3070 ti, and load times are considerably faster, like 5x faster, but I still prefer playing on PS5.
Edit: there have been a few times on PS5 where particles don't load. I walked right into a poison cloud because it wasn't visible on the screen once, and another time some ambient SFX were missing. One time one of the characters was missing her armor and hair. That was funny. But those experiences have been far and few in-between, and a restart fixes it.