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They would die immediately.
Breaking atomic and molecular bonds is what ionizing radiation such as gamma rays or neutrons does to a human body, so this scenario would be sort of like an extreme, unrealistically high dose of radiation.
Immediately after all bonds are broken, atoms would react and start to form new bonds. In some cases these bonds would reform correctly- for example, water being remade as H2O. In many cases alternative bonds would form which could make substances incompatible with life- say H2O2, aka hydrogen peroxide. Basic cellular and nerve function wouldn’t work, hence the instant death.