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Controller boot into gaming
(lemmy.world)
Discussions and news about gaming on the GNU/Linux family of operating systems (including the Steam Deck). Potentially a $HOME away from home for disgruntled /r/linux_gaming denizens of the redditarian demesne.
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Original /r/linux_gaming pengwing by uoou.
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I think the bigger hurdle here is that you need to do some legwork and research, else you would not be here asking this question 😉
It's possible but then I'd ask why? What's the purpose of booting a different DE based on the controller type?
My guess is that they want only the necessary software to run when gaming, which KDE is not. But I'll let OP speak for themselves.