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Booting to Steam Big Picture under certain conditions
(lemmy.world)
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As a workaround, if you have a Steam Controller pressing the Steam button should bring up Steam and pressing it again should switch to Big Picture Mode. That's at least how it works on my Steam Deck in desktop mode.
If you have an Xbox or PlayStation controller you could try if their corresponding buttons work the same.
I might try that, the only issue is having it pop up on the right display, since my main desktop monitor I set as the primary. Presumably will need to script that anyway