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Israel: White Phosphorus Used in Gaza, Lebanon
(www.hrw.org)
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Oh OK, my cursory search turned up Hexachloroethane which is only classed as an irritant, but I thought maybe you knew of a reason that wasn't appropriate to use.
I saw that as an alternative but at least according to wikipedia:
Leave it to the cops to use something the army is phasing out as too dangerous domestically on protestors