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Anyone ever have a baked potato explode?
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It's not just that. Ovens cook with heat originating outside of the food, so the skin cooks(and cracks) before the inside gets hot enough to detonate. Microwaves on the other hand cook by exciting water molecules inside the food, and since the inside of the potato has way more moisture than the skin, it heats up much faster than the skin does.
Microwaves still cook from the outside in, but yes, mostly only excite water.
I believe this came up in another ATK thing, but can't track it down at the moment.