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Good NAS Software for a Bad PC?
(sopuli.xyz)
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First of all, 4 GB is not so bad, I ran with 4 GB on mine for years. In fact I'm still not using more than 4 GB even though I have more RAM now, it still takes 3.7 GB right now and I run 20 containers.
I don't run Nextcloud though, and I don't run VM's. VM's definitely would need more RAM, and I don't know how much Nextcloud wants. Syncthing wants very little.
Think about why do you want a GUI, they don't typically offer that much if you already know your way around Linux. And once you set up a container it will keep working indefinitely (until you upgrade it anyway, but that's another kettle of fish).
You also don't need anything fancy to put together a RAID1 out of those two disks, if that's what you mean to do.