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Tailscale/synology/NFS remote access
(lemm.ee)
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All fantastic suggestions, btw, but my hair-pulling is coming from none of them working (other than autoblock). :)
Does ping work? Have you validated tailscale?
Check the iptables on the device.
If that doesn't work it's time to do tcpdumps on the different internal interfaces of the Nas and see where it stops