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Steam Families is here
(store.steampowered.com)
Steam is a video game digital distribution service by Valve.
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Issue tracker for Linux version of Steam
How does this effect that?
My guess is this, which is way at the bottom of the support FAQ page (which can be found at the bottom of the posted FAQ section):
"I cannot join a Steam Family"
If you cannot join a Steam Family, it is likely for one of three reasons:
I cannot invite my gf to the Families, while we could do Library share before just fine.
Why not?
Replied in other posts, it likely is because you have to be in the same country/steam store region or something...
A lot of work but: have her VPN into your residential network and send her traffic through your ISP for a while.
5head tactics haha.
Just sign in with her account on your pc, invite her and then you can sign out. I had the same problem.