It probably works with some tinkering. I would recommend completing it once the way the modders intended since they likely never tested their game with VR in mind.
It is actually a Skyrim mod but basically a complete game that just happens to be built upon Skyrim. It features full professional quality voice acting in German and English, new game systems inspired by the Gothic series, a setting separate from Elder Scrolls, and a story that gets close to the quality of Planescape Torment or Disco Elysium. I can't recommend it enough.
Only way to find out is to try it. Something like Club Penguin shouldn't give you much trouble especially if you use a launcher like Lutris.
Neat, but sad to see that it is permissively licensed.
I remember that series, it was basically Myst but as a learning game. I played a bit of 'Chemicus' as a child but also never got far. These games where probably all way to hard for children. I wonder, do learning games even exist anymore? I spent many hours with games like 'The Mystery of Mathra'.
Now I got the Tivola jingle stuck in my head. My very first PC game was a Tivola game. It seems they really fell from grace in recent years when looking at their website today.
The silverblue docs explain it best: