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How the latest execution method is always humane, while the last one was barbaric:
Yeah the difference is this method is actually promoted by the scientific community, rather than commercial interests. Nitrogen suffocation is used for assisted suicide.
I just wish we'd use it for pork. However because it's so hazardous to humans (boiling nitrogen releases gas that expands very quickly and expells all the oxygen in the room) we just stick with CO2, which is very easy because it's heavier than air so you just have walkways to protect the people. With nitrogen, they'd require much more expensive safety measures to protect people working nearby. Also, CO2 causes a feeling of suffocation, leading to the pig lashing about and suffering, and possibly spoiling the meat somewhat.
Electrocution is perhaps the worst. They actually limit the current, meaning it kills you a little more slowly or maybe not at all, because if they went full power they would literally cook the person and that would smell unpleasant for everyone else. Lethal injections aren't much better, typically they paralyse the person first so they can feel themselves dying but not move to show any sign of it.
I'm certainly keen to learn of any further downsides to nitrogen, but as far as I'm aware it's the best thing going (out of a horrible bunch of ways to kill). Like I said before, I'm against the death penalty as a rule, but if you're going to do it then it should be as painless as possible.