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Are there any green alternatives to asphalt in development?
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No, it's been through serious development, with several projects and grants through the US government (US DoT/FHA, US DoE). But in all testing, it's had multiple safety issues for car traffic (durability issues with the lighting elements that make up the road markings, for one example) that has kept it from any possible approval as an actual high-capacity road surface.
They haven't had any sustained or spreading success because they keep shooting for the hardest goal... but likely they'll have to eventually scale back if they want to gain any traction (no pun intended).
It's also a stupid place to put solar panels. Just put them alongside the road.