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I always thought suicide bags with nitrogen or helium were the way to go. I didn't read why the last guy had such a miserable death, but I did read it wasn't pretty.
I feel like they could put someone under some anesthesia and finish the job with the gas. Or even better, don't kill people, like you said.
Generalized convulsions are a pretty well-established effect of nitrogen toxicity.
"In the few experiments in which nitrogen was breathed for 17–20 sec unconsciousness supervened and was accompanied on most occasions by a generalized convulsion."
https://en.m.wikipedia.org/wiki/Inert_gas_asphyxiation
Known in the scuba diving world as "getting narced" (nitrogen narcosis)
https://www.scuba.com/blog/dealing-nitrogen-narcosis-2/
"In severe cases, divers have been known to experience convulsions, possibly causing loss of consciousness in extreme cases."