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Nutritional Hexes
(mander.xyz)
A place for majestic STEMLORD peacocking, as well as memes about the realities of working in a lab.

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This is a science community. We use the Dawkins definition of meme.
Absolutely true, and getting good data is really, really hard. In fact, the nutritional content on food labels (in the USA) is allowed to be over by as much as 20% by the FDA.
In addition to that the processes and formulas used to calculate those numbers are also far from precise .
However, this is only an estimate because not everything that burns and releases energy to heat the water can be digested by a person eating it. Fiber, for example, burns in the calorimeter but will just pass through your digestive system without giving up its energy.
Many food companies don't even test food like this. They simply estimate the calorie content based on the number of grams of fat, carbs, and proteins in the food. Still, unless and until someone comes up with a better way to determine the calories in a given measure of food, it's the best system we've got.
I'd also be willing to bet that the actual amount of calories someone gets from different kinds of food is dependent on their gut biome, and thus variable between people. Ime you really need to experiment on yourself to get a good idea of what will make you lose weight. Same probably applies if you're underweight and trying to gain.