No way. iPhones don't exactly allow bootloader unlocking to begin with, but even if you could, it would be in no better state than Asahi on the M1 Apple computers. Every driver would have to be written from scratch.
Pixels are a good platform for custom ROMs because until the recent drama, you could literally just build AOSP as-is and use it. So the GrapheneOS team only really need to focus on their changes to the OS and their apps and none of the drivers and modem interface and all that. That's also why GrapheneOS runs so well on it: Google provided everything, it just works.
iPhones would be the absolute worst phone to develop for: zero support from Apple, no drivers no documentation, no nothing. Not even a Linux kernel! At least for Android, the Linux license forces manufacturers to publish the source code, so at minimum you start with something that should boot and contain all the stuff to talk to the hardware already, just need to wire it in with userspace drivers. CPU manufacturers like Qualcomm also provide a fair chunk of the userspace drivers open-source too, so you can just pull that and have audio and video working.
Not impossible, but definitely really hard and impractical.